Isomerization polymerization of 4-alkylcyclopentenes catalyzed by Pd-diimine complexes produces the polymers with trans-1,3-disubstituted cyclopentane rings located regularly along the polymer chain. The polymers with isotactic structure formed by using a C(2)-symmetric catalyst exhibited liquid-crystalline properties.
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Okada et al. (2009) studied this question.
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