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A series of trinuclear and dinuclear Cr(I)–N 2 complexes bearing cyclopentadienyl-phosphine ligands were synthesized and characterized. Further reduction of the Cr(I)–N 2 complexes generated anionic Cr(0)–N 2 complexes, which could react with Me 3 SiCl to afford the first chromium hydrazido complex from N 2 functionalization. These complexes were found to be effective catalysts for the transformation of N 2 into N(SiMe 3 ) 3 .
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Yin et al. (2019) studied this question.
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