Copolymerization of propylene System name: propene. and 1‐alkenes (1‐octene, 1‐decene, 1‐dodecene, 1‐tetradecene, 1‐hexadecene) were studied with the catalyst system MgCl2/TiCl4‐Al(i‐Bu)3. It was found that the polymerization productivity and the consumption rate of propylene are improved significantly in the presence of the comonomer. The total productivity of propylene/1‐alkene copolymerizations decreases as follows: 1‐octene > 1‐decene > 1‐dodecene > 1‐hexadecene > 1‐tetradecene. The reactivity ratios were estimated from the copolymerization results.
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Xu et al. (1991) studied this question.
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