October 22, 2003Angewandte Chemie

[Cp(η2‐bipy)(MeCN)RuII][PF6] Catalysts for Regioselective Allylic Substitution and Characterization of Dicationic [Cp(η2‐bipy)(η3‐allyl)RuIV][PF6]2 Intermediates

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Abstract

Ausgehend von 2,2′-Bipyridinderivaten als Liganden für (C5Me5)RuII-Komplexe wurden neue dikationische RuIV-Allyl-Komplexe (Beispiel siehe Bild) und hoch effiziente Katalysatoren für die regioselektive Allylierung mit unsymmetrischen Allylkohlensäureestern hergestellt.

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Mbaye et al. (2003) studied this question.

synapsesocial.com/papers/6a8a7756788d49930fcc009c https://doi.org/10.1002/ange.200352257

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[Cp(η2‐bipy)(MeCN)RuII][PF6] Catalysts for Regioselective Allylic Substitution and Characterization of Dicationic [Cp(η2‐bipy)(η3‐allyl)RuIV][PF6]2 Intermediates

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[Cp(η2‐bipy)(MeCN)RuII][PF6] Catalysts for Regioselective Allylic Substitution and Characterization of Dicationic [Cp(η2‐bipy)(η3‐allyl)RuIV][PF6]2 Intermediates

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[Cp*(η2‐bipy)(MeCN)RuII][PF6] Catalysts for Regioselective Allylic Substitution and Characterization of Dicationic [Cp*(η2‐bipy)(η3‐allyl)RuIV][PF6]2 Intermediates

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Discussion

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[Cp*(η2‐bipy)(MeCN)RuII][PF6] Catalysts for Regioselective Allylic Substitution and Characterization of Dicationic [Cp*(η2‐bipy)(η3‐allyl)RuIV][PF6]2 Intermediates

Abstract

Discussion

Cite This Study

Keep reading

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[Cp(η2‐bipy)(MeCN)RuII][PF6] Catalysts for Regioselective Allylic Substitution and Characterization of Dicationic [Cp(η2‐bipy)(η3‐allyl)RuIV][PF6]2 Intermediates

[Cp(η2‐bipy)(MeCN)RuII][PF6] Catalysts for Regioselective Allylic Substitution and Characterization of Dicationic [Cp(η2‐bipy)(η3‐allyl)RuIV][PF6]2 Intermediates