A systematic investigation of dipole moment and tensor polarizability autocorrelation functions is undertaken for liquid CHCl3, CHBr3, CDCl3 and CDBr3. Application of Bratos' theory to pure liquid haloforms is tested by a study of isotopically diluted solutions. Vibrational, τv , and orientational, τR , relaxation times are given for the v 1 band and its overtones. The τR values reveal that the tumbling motion is identical for CHCl3 and CDCl3 as well as for CHBr3 and CDBr3. It appears that rotation-vibration coupling is negligible.
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Brodbeck et al. (1976) studied this question.
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