The novel air- and moisture-stable dihydrido(methyl)platinum(IV) complex TpPtH 2 Me ( 1; Tp = hydridotris(pyrazolyl)borate) is formed as the sole product by the reaction of TpPtMeCO ( 2 ) with water. Complex 1 was characterized by elemental analysis, 1 H NMR, 13 C NMR, and FTIR. The proposed mechanism of the reaction involves an initial nucleophilic attack by a water molecule on the coordinated carbonyl in 2 with subsequent release of CO 2 followed by protonation at the platinum center to produce 1 .
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Haskel et al. (1999) studied this question.
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