Hydrogen Balmer lines were observed in the plasma of a plane-cathode abnormal glow discharge in mixtures of argon or neon with hydrogen and in pure hydrogen. Intense spectral-line wing development was detected whenever argon was present in the plasma. This effect is related to the formation of H₂⁺ ions in a charge-transfer reaction between metastable Ar⁺ and H₂ molecules.
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Kuraica et al. (1992) studied this question.
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