Rapid liquid phase sintered Mn doped BiFeO3 ceramics with enhanced polarization and weak magnetization

Single-phase BiFe1−xMnxO3 multiferroic ceramics have been synthesized by rapid liquid phase sintering method to study the influence of Mn substitution on their crystal structure, dielectric, magnetic, and ferroelectric behaviors. From XRD analysis it is seen that Mn substitution does not affect the crystal structure of the BiFe1−xMnxO3 system. An enhancement in magnetization was observed for BiFe1−xMnxO3 ceramics. However, the ferooelectric hysteresis loops were not really saturated, we observed a spontaneous polarization of 10.23μC∕cm2 under the applied field of 42kV∕cm and remanent polarization of 3.99μC∕cm2 for x=0.3 ceramic.