RF magnetron sputtering from a single YBCO target onto a heated substrate ( approximately=700 degrees C) was used to obtain c-axis-oriented 1-2-3 films that are superconducting without a subsequent annealing or oxygenation step, with T/sub c/(R=0) as high as 88 K on MgO and LaAlO/sub 3/ substrates. This process uses an 8-in-diameter target in the sputter-up configuration, with a central grounded shield to eliminate negative ion bombardment. It can reproducibly and uniformly cover substrates as large as 3-in across at rates exceeding 1 AA/s. Maintaining film composition very close to stoichiometry is essential for obtaining films with good superconducting properties and surface morphology. Optimum films have critical currents of approximately=1 MA/cm/sup 2/ at 77 K. Measurements of microwave surface resistance based on a stripline resonator indicate low surface resistance for unpatterned YBCO ground planes, but excess loss and a strong power dependence in a patterned center strip.
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Ballentine et al. (1991) studied this question.
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