CuxAgyInzZnkSm solid solutions, customized with RuO2 or Rh1.32Cr0.66O3 co-catalyst with a small energy band gap <2 eV were studied for photocatalytic CO2 reduction to CH3OH under visible light. Significantly, 118.5 µmol g−1 h−1CH3OH yield was obtained with RuO2/Cu0.30Ag0.07In0.34Zn1.31S2 under hydrogen effect.
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Liu et al. (2011) studied this question.
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