The HgXe excimer band at 270 nm has been studied in fluorescence following optical excitation of the Hg 3P1 level. From the temperature dependence of the normalized fluorescence band shape, the potential curves of the 3O+ excimer state and the 1O+ ground state are inferred. A binding energy of 1400±100 cm−1 is found for the 3O+ state.
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Lam et al. (1978) studied this question.
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