Chemical Kinetic Data Sheets for High-Temperature Reactions. Part II

Rate coefficient measurements for over fifty gas-phase bimolecular reactions were critically evaluated and compared to theoretical calculations. The results of this work are summarized here in forty-nine Data Sheets, one sheet for each reaction or set of reactions of a single pair of reagents. The reactions chosen are of interest in propulsion, combustion, and atmospheric chemistry. Each Data Sheet consists of two pages that include a brief resumé of the important experimental measurements and theoretical calculations, a graphical presentation of the data, a recommended rate coefficient expressed as a function of temperature, k(T)=ATnexp(−BT), with probable uncertainty limits, a discussion of the basis for the recommendation, an equilibrium constant and a rate coefficient for the reverse reaction where applicable, and pertinent references.