Emulsions are not necessarily thermodynamically unstable. Here it is shown that thermodynamically stable states of self-assembled supra-aggregates exist, and that the component ratios and microstructures that form can be predicted quantitatively from elementary arguments. The Figure is a freeze fracture image of one of the phases that forms when copper(II) bis(2-ethylhexyl)sulfosuccinate is mixed with isooctane and water.
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André et al. (2000) studied this question.