Precision gas mixing pumps produce CO(2) gas mixtures for the calibration of infra-red CO(2) gas analyzers equivalent in accuracy to the standard CO(2) gas mixtures (+/- 1%) supplied by the National Bureau of Standards, Washington, D. C.The calibration of infra-red gas analyzers by the pressure difference method and by concentration differences did not agree. A factor of 0.709 was necessary to correct the pressure difference method for the effects of pressure broadening with our analyzer.
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Bate et al. (1969) studied this question.
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