June 21, 2006Angewandte Chemie

Short Synthesis of (+)‐Cylindricine C by Using a Catalytic Asymmetric Michael Reaction with a Two‐Center Organocatalyst

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Abstract

Zwei zum Preis von einem: Die Totalsynthese von (+)-Cylindricin C gelang in sechs Stufen mithilfe einer katalytischen asymmetrischen Michael-Reaktion und einer Tandem-Cyclisierung. Ein neu entwickelter Zwei-Zentren-Organokatalysator ermöglicht diese Michael-Reaktion mit guter Selektivität. TaDiAS=von Tartrat abgeleitetes Diammoniumsalz.

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Shibuguchi et al. (2006) studied this question.

synapsesocial.com/papers/6a8aa8a893d6d5583ccc1c2b https://doi.org/10.1002/ange.200601722

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Short Synthesis of (+)‐Cylindricine C by Using a Catalytic Asymmetric Michael Reaction with a Two‐Center Organocatalyst

Abstract

Discussion

Cite This Study

Short Synthesis of (+)‐Cylindricine C by Using a Catalytic Asymmetric Michael Reaction with a Two‐Center Organocatalyst

Abstract

Discussion

Cite This Study

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