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Spectroscopic measurements of the electron-hole fluid in Ge indicate that the liquid-gas phase diagram is distroted from that of simple fluids. This Mott distortion appears as a broadening of the top of the phase diagram with gas densities at least a factor of 3 lower than expected in the region near the Mott density. The precise shape of the phase boundary in the high-density gas remains uncertain because of inadequacies in our theoretical and experimental understanding of screening effects at finite temperatures. However, no first-order Mott transition separate from the liquid-gas transition is found to occur.
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Thomas et al. (1978) studied this question.
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