The addition of o-carboranyltributyltin 1 to aldehydes 2 is catalysed by [Pd2(dba)3]·CHCl3, (dba = dibenzylideneacetone) giving the corresponding adducts, 1-(o-carboranyl)-1-methanol derivatives 3, in good to high yields.
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Nakamura et al. (1994) studied this question.
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