Bichromophoric Perylene Derivatives: Energy Transfer from Non-Fluorescent Chromophores

The energy of excitation at non-fluorescent chromophores such as fluorenone and anthraquinone has been trapped by a fast energy transfer to the highly fluorescent perylene bisimides. To this end, anthraquinone, fluorenone and anthracene derivatives have been linked to the perylene bisimides by non-conjugating spacers and fluorescence quantum yield of such assemblies have been determined as a function of the wavelengths of excitation. Energy transfer in such assemblies is strongly influenced by the orientation of the two chromophores. This is of interest for the construction of fluorescence switches.