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The kinetics of the dimerization of butadiene and of the dissociation of vinylcyclohexene have been considered in the light of thermodynamic equilibrium calculations. The lack of accord between the results is resolved if the dissociation of vinylcyclohexene is given by the rate expression kd=5.02×1015exp(−61,800/RT) sec−1.
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Duncan et al. (1952) studied this question.
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