The discharge reaction taking place within the confinement of an experimental analog, simulating porous electrode behavior, is examined in terms of the solution‐precipitation path for the system. A scanning electron microscopic (SEM) investigation, combined with an analytical treatment of a simplified model of nucleation and growth processes, provided a connection between the shape of individual crystallites and the form of the duplex oxide film. It was shown that the coupling between the growth kinetics and local transport is instrumental in the development of observed morphologies.
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Szpak et al. (1979) studied this question.
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