Thin-film PbTe diode lasers are used for Doppler-limited Stark spectroscopy on the nu(4) vibration-rotation band of NH(3) in the 1545-1595-cm(-1) region. The lasers operate cw below 20 K and are frequency tuned by varying the diode current. The nu(4) excited state dipole moment of NH(3) is found to be about 1% less than the ground state value.
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Weber et al. (1974) studied this question.
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