Photoreduction: Defect‐Rich Ultrathin ZnAl‐Layered Double Hydroxide Nanosheets for Efficient Photoreduction of CO2 to CO with Water (Adv. Mater. 47/2015)

Catalysts with coordinatively unsaturated Znd+ (d < 2) centers have recently attracted attention for the photocatalytic dehydrogenation of methane. On page 7824, T. Zhang and co-workers report that Zn+–Vo complexes are introduced by synthesizing ultrathin ZnAl-layer double hydroxide nanosheets, which exhibit extraordinarily high activity for the photoreduction of CO2 to CO with water.