A three-component homogeneous catalyst system, composed of a cyclometalated iridium(iii) photosensitizer, a bioinspired diiron complex, and TEA in aqueous acetone, proved to be catalytically active for photoinduced H(2) production, with up to 660 turnovers over 8 h of irradiation.
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Zhang et al. (2009) studied this question.
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