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May 1, 2004Inorganic Chemistry

H2 Activation in Aqueous Solution: Formation of trans-[Fe(DMeOPrPE)2H(H2)]+ via the Heterolysis of H2 in Water

John D. Gilbertson Nathaniel K. Szymczak David R. Tyler

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Abstract

The water-soluble iron phosphine complex trans-Fe(DMeOPrPE)(2)Cl(2) (DMeOPrPE = 1,2-bis(bis(methoxypropyl)phosphino)ethane) reacts with H(2) in water to produce trans-[Fe(DMeOPrPE)(2)H(H(2))](+) and H(+). The product is a water-soluble eta(2)-H(2) metal hydride complex, formed via the heterolysis of coordinated H(2) in water.

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Gilbertson et al. (2004) studied this question.

synapsesocial.com/papers/6a8b8ce68c20842028339ce9 https://doi.org/10.1021/ic0498642

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