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Triglycerides containing acids withtrans‐3 unsaturation (16∶13, 18∶13 and 18∶33, 9, 12) showed a marked retardation of reaction rate with pancreatic lipase. An inverse relationship was found between content oftrans‐3 unsaturated acids in seed oils and lipolysis rate. Thetrans‐3 unsaturated acids were concentrated in the diglyceride and residual triglyceride fractions of the lipolysates, and only small amounts were present in the free acid and monoglyceride fractions.
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Kleiman et al. (1970) studied this question.
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