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Structural analysis demonstrates the synthesis of dinuclear copper(I) benzoquinone complexes, indicating enhanced pi-back-donation in copper-based catalytic systems.
Novel Cu(I) complexes containing a mu2-eta2,eta2-type benzoquinone ligand have been synthesized and crystallographycally characterized. These complexes are synthesized by the redox reaction of a copper-quinonoid pair and may indicate a significant intermediate in the Cu-BQ catalytic system. Moreover, this study is regarded as one of the good examples in the Cu(I)-olefin family of enhanced pi-back-donation.
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Masaoka et al. (2003) studied this question.
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