A direct synthesis of acylmetals from alkynes with group 14 metal hydride and CO is reported. The Pd(0)-catalyzed reaction of alkynes with tri(2-furyl)germane under ambient pressure of CO provides alpha,beta-unsaturated acylgermanes in good yields. Conversion of acylgermanes to the corresponding amides is achieved.
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Kinoshita et al. (2002) studied this question.
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