Hydrogen bonds to metal complexes located within the active sites of proteins have been implicated in the regulation of function. Incorporation of these noncovalent interactions into a synthetic system with bridging oxo ligands is reported. Unprecedented thermal stability of a complex with a {CoIII(μ-O)2CoIII} core is observed (see picture), in which intramolecular hydrogen bonds to the oxo ligands are present.
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Larsen et al. (2003) studied this question.
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