The chain compound (SN) x is the first example of a superconducting polymer. In this paper we review the chemistry, structure, and physical properties of (SN) x and describe how the electrical properties of this novel material depend upon the crystal growth technique. The thermal properties of S 2 N 2 and (SN) x are discussed with particular reference to the crystal growth process. The fibrous nature of the polymer is described and evidence is presented showing that interchain coupling plays a significant role in determining the physical properties of this material. Finally we summarize our attempts to prepare analogous polymeric metals.
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Street et al. (1977) studied this question.
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