A hexagonal prism, in which the two parallel six-membered rings of alternating Mg and N atoms are almost planar, forms the molecular framework of the title compound (Ph and THF substituents are represented by ipso-C and O atoms, respectively, in the picture shown on the right). This compound, which can be readily synthesized from Et2Mg and H2NPh in ether, is the first well-characterized magnesium imide.
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Hascall et al. (1994) studied this question.
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