No need for a metal: A combination of mass spectrometry and computational studies (density functional theory and coupled-cluster methods) shows that [P(4)O(10)](.+) is the first polynuclear nonmetal oxide cation that is capable of activating the C--H bond of methane at room temperature (see picture). This process represents a further example in the reactivity of oxygen-centered radicals.
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Dietl et al. (2009) studied this question.
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