December 14, 2000Inorganic Chemistry

Ferromagnetically Coupled Bis(semiquinone) Ligand Enforces High-Spin Ground States in Bis-metal Complexes

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ACAndréa CaneschiIstituto Nazionale di Fisica Nucleare, Sezione di Firenze ADAndrea DeiUnited States Nuclear Regulatory Commission HLHyoyoung LeeSungkyunkwan University

Abstract

The π-connectivity of a bis(semiquinone) ligand enforces ferromagnetic coupling between the two semiquinone halves of the molecule. Using the ligand in connection with paramagnetic metal ions leads to complexes with S = 3 (M = NiII), S = 2 (M = CuII), and S = 2 (M = CrIII) ground states.

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Caneschi et al. (2000) studied this question.

synapsesocial.com/papers/6a8c05fbfe910689a2894150 https://doi.org/10.1021/ic000440r

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Ferromagnetically Coupled Bis(semiquinone) Ligand Enforces High-Spin Ground States in Bis-metal Complexes

Abstract

Discussion

Cite This Study

Ferromagnetically Coupled Bis(semiquinone) Ligand Enforces High-Spin Ground States in Bis-metal Complexes

Abstract

Discussion

Cite This Study

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