We report on a new method based on the combination of Langmuir–Schaefer deposition with self-assembly to insert highly anisotropic Ni 8 molecules in a hybrid organic–inorganic nanostructure. Spectroscopic, crystallographic, and magnetic data prove the successful insertion of the guest cationic molecule between templating clay platelets. These results open a new route toward the highly controlled fabrication of tailored functional organic–inorganic nanomaterials.
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Toma et al. (2011) studied this question.
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