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A useful and effective rhodium catalyst system – [RhCl(PPh3)3/DPPF] – for the Suzuki–Miyaura cross‐coupling of activated alkenyl tosylates is described. The results not only represent the first examples of the rhodium‐catalyzed Suzuki–Miyaura coupling of activated alkenyl tosylates with arylboronic acids under mild conditions, but also provide an efficient route for the synthesis of some natural product‐like compounds, such as furan‐2(5H)‐one, coumarin, pyrone, and quinolin‐2(1H)‐one derivatives.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)
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Wu et al. (2006) studied this question.
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