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The gelation rate of poly(vinylidene fluoride) (PVF2)/glyceryl tributyrate (GTB) system has been measured. It has been analysed with the help of an equation which contains φn and f(T) term where φ is a reduced overlapping concentration and n is analogous to the percolation exponent β in a three‐dimensional lattice. f(T) is related to the temperature function of the coil‐to‐helix transition. Analysis of the gelation rates supports that the three‐dimensional percolation is a suitable mechanism in this gelation process and it also indicates that the gelation is caused by coil‐to‐helix transition followed by their association.
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Mal et al. (1997) studied this question.
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