A vanadium-doped porous titania rich in active hydrogen (V-TiO(2)(H*)) has been successfully prepared and demonstrated to be an efficient and green reductant with renewable capacity. This V-TiO(2)(H*) material can instantly (<10 s) and selectively reduce nitroarenes to aminoarenes under ambient conditions without catalysts.
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Su et al. (2012) studied this question.
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