Smart nanochannels: tailoring ion transport properties through variation in nanochannel geometry

This research explores ion transport behavior and functionality in a hybrid nanochannel that consists of two conical and cylindrical parts. The numerical investigation focuses on analyzing the length of each part in the nanochannel. The nanochannels are hybrid cavities embedded in a membrane, where the size of the conical part varies as equal to, larger than, or smaller than the cylindrical part. The nanochannel is coated with a polyelectrolyte layer that exhibits a dense charge density distribution. The charge density of the soft layer is described using the soft step distribution function. We study the electroosmotic flow, ionic current, rectification, and selectivity of the nanochannel