Twelve electrons more than the starting material, but the same cluster framework—this modification was achieved for the first time in the synthesis of the Pt3Re clusters 1 (66e) from [Pt3{Re(CO)3}(μ-dppm)3]+ (54e) and H2O2 or propene sulfide. The metal-oxygen units in 1 could serve as models for the interactions between oxo ligands and metal clusters, which are important in oxide-supported PtRe bimetallic catalysts.
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Hao et al. (1995) studied this question.
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