Evidence of Acid-Base Interfacial Adducts in Various Polymer/Metal Systems by IRAS: Improvement of Adhesion

The physical interactions of polymers with inorganic substrates are determined by two major contributions: Van der Waals forces and acid-base interactions, taken in the most general “Lewis” electron acceptor-donor sense. The present work shows that the work of adhesion can be very appreciably increased by the creation of interfacial acid-base interactions. Practically, polymers such as poly(ethylene-co-vinyl acetate) (EVA), terpene-phenol resins (TPR), and their blends, were solution cast on basic and acidic substrates. The nature of the interfacial bonds and the enthalpy of adduct formation through electron exchange are evidenced by Fourier transform infrared reflection-absorption spectroscopy (IRAS). Moreover, it is shown that, on the one hand, modification of the electron donor ability of the polymer functionalities reveals the amphoteric character of the substrate and, on the other hand, modification of the electron donor ability of the substrate changes the nature of the species involved in interfacial adduct formation. Then, practical adhesion tests were carried out in order to correlate the nature and strength of interfacial acid-base bonds with simultaneous increases in adhesive strengths. Thermodynamic considerations allowed us to propose estimated values of the acid-base work of adhesion, Wab , and of the density of acid-base sites, nab .