The first observation of a long Rydberg series due to single excitation from the 4f 14 subshell in Yb I is reported. A two-channel MQDT analysis reveals a prominent series perturbation due to coupling with one particular 4f 14 5dnf doubly excited series. The J c j designations of both channels are shown to be consistent with the occurrence of this particular interaction.
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Baig et al. (1984) studied this question.
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