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Reactions of the antitumour complex [Rh2(O2CMe)4] with adenine nucleosides and nucleotides have been studied in aqueous solutions. Both 1 : 1 and 1 : 2 solid adducts have been isolated and characterized by elemental analyses and i.r., visible, and 1H n.m.r. spectra. The results indicate that the 1 : 1 adenine derivatives form polymeric bridged adducts with both N(1) and N(7) sites bonded to RhII. The only exception is tetra-acetyladenosine which forms 1 : 2 adducts in which only the N(7) site is involved in bonding to RhII.
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Pneumatikakis et al. (1979) studied this question.
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