PtPtClPtPt plus ligand—this epitomizes the structure of the cation of the title compound: cis-[{(NH3)2Pt(MeT)2PtCl2}2]Cl2⊕; MeT is thereby the anion of 1 -methylthymine. This novel mixed valence platinum(2.75) complex formally contains three PtIIIcenters and one PtIIcenter. A PtPt unit together with ligands and bridging chlorine atom is pictured on the right.
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Renn et al. (1990) studied this question.
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