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The double-nucleophilic attacks of methanol and water successively on the two carbon atoms of a double bond of olefins was realized on a Pt(III) dimeric complex to give the corresponding dinucleophile-substituted alkanes for the first time. Formation of the intermediate diplatinum(III) β-methoxy and β-hydroxyalkyl complexes was confirmed.
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Lin et al. (1999) studied this question.
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