This is the first report of biomimetic aerobic polymerization of vinyl monomers, which has been achieved under mild conditions. When a homogeneous solution of a vinyl monomer containing a reversible oxygen carrier, namely 5,10,15,20 tetraphenyl-21H, 23H-porphinecobalt(II) pyridine complex [CoTPP(Py)], is exposed to air at room temperature, an alternating copolyperoxide is obtained (eq 1).
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K. Kishore (1998) studied this question.
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