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Identification of the free radicals in polyethylene and nylon produced by irradiation, grinding, and pulling to fracture was carried out by comparing the experimentally observed spectra with the spectra constructed from theoretical consideration with the aid of a computer. It was demonstrated that the various primary and secondary radicals are produced and formed in the materials depending upon means of degradation, degradation processes, orientation of materials, and conditions of ESR measurement.
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M. Igarashi (1983) studied this question.
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