Three types of photochemical reaction of coordination compounds are well‐known and have often been discussed: redox reactions, substitutions, and isomerizations. Less well known is a fourth type of reaction, which occurs fairly frequently: reaction of the ligands themselves. It is the purpose of this article to fill the corresponding gap in the photochemical literature and to summarize our current knowledge of such reactions and of their mechanisms and possible applications.
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Poznyak et al. (1988) studied this question.
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