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While double bonds are known for transition metals of Groups 9 and 10 as well as for boron and p‐block elements of Groups 14–16, Zn sits in a small region of the periodic table with no well‐characterized double bonds. A qualitative reasoning indicates that zero‐valent zinc has the potential to form Zn=Zn double bonds. A computational study in search for complexes that might showcase this new bond type is presented here.
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Echeverría et al. (2017) studied this question.
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