The volume compression of tantalum was measured to 174 GPa in a diamond-anvil cell using angle-resolved synchrotron x-ray diffraction. A third-order Birch-Murnaghan equation-of-state constrains the compression data rather well with the zero-pressure isothermal bulk modulus B0T=194.7(4.8)GPa and the first pressure derivative B^'=3.4(0.1). These values are consistent with the previous ultrasonic results, B0S=196GPa and B^'=3.8, but are different from the previous x-ray compression results, B0T=231GPa and B^'=2.5. The current compression data also demonstrate that the bcc phase of Ta continues to be stable to 174 GPa, which qualifies tantalum for a pressure standard in static high-pressure experiments.
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Cynn et al. (1999) studied this question.
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