Abstract pKa Values of 42 quinuclidinium perchlorates I have been measured in 0.1 M aqueous KCl‐solution. In a few cases small corrections of earlier thermodynamic pKa values are indicated. These measurements, in conjunction with recent X‐ray structure determinations, confirm the reliability of the inductive substituent constants σIq derived from them.
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Grob et al. (1980) studied this question.
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