A water-stable 3D luminescent metal–organic framework (MOF), [Eu 6 Zn(μ 3 -OH) 8 (NDC) 6 (H 2 O) 6 ] n ( 1 ), constructed from heterometallic [Eu III 6 Zn II ] clusters and electron-rich π-conjugated 1,4-naphthalenedicarboxylic acid (H 2 NDC) ligands exhibits highly sensitive, selective, and reversible detection of ronidazole, which represents the first example of luminescent MOFs based on Ln-TM heterometallic clusters for the detection of antibiotics in aqueous solution.
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Zhang et al. (2017) studied this question.
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